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How does strength of boric acid solution increase in presence of salicylic acid?
Mechanism of Acidity - Boric AcidThe acidity of boric acidBoric Acid - Mechanism of AcidityHow to recrystallize boric acid into flakes?How to Determine Acid Strength?Why is boric acid soapy to touch?How to Prepare a Buffer Solution?Basicity of boric acidPicric Acid from Salicylic AcidCan ethylene glycol enhance the acidity of orthoboric acid?
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
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add a comment |
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A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
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$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago
add a comment |
$begingroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
A while ago, I read that salicylic acid can make boric acid solution strongly acidic when it's added to it.
To my knowledge, I know that boric acid becomes a strong acid in presence of cis-diols (except ethylene glycol). I also know that it happens due to increased stability of conjugate base by chelation using polyhydroxy compounds.
But I can't really make out the case with salicylic acid. I will be really thankful if you could shed some light on this topic.
inorganic-chemistry acid-base
inorganic-chemistry acid-base
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
New contributor
Richeek is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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edited 17 hours ago
andselisk
19k660125
19k660125
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asked 20 hours ago
RicheekRicheek
383
383
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$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago
add a comment |
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago
$begingroup$
see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago
add a comment |
2 Answers
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oldest
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Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
$endgroup$
add a comment |
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2 Answers
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active
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2 Answers
2
active
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active
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$begingroup$

Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421
$endgroup$
add a comment |
$begingroup$

Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421
$endgroup$
add a comment |
$begingroup$

Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421
$endgroup$

Equilibrium will be far to the right, as a stable six membered ring is formed. The proton speaks for itself.
References: A. Queen, Canadian Journal of Chemistry, 1977, 55(16): 3035-3039, https://doi.org/10.1139/v77-421
edited 17 hours ago
answered 19 hours ago
William R. EbenezerWilliam R. Ebenezer
66914
66914
add a comment |
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
$endgroup$
add a comment |
$begingroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
$endgroup$
By googling "boric acid salicylic acid"
I have found the salicylic acid acts like it was a diol toward the boric acid, but just 1:1.
https://www.nrcresearchpress.com/doi/abs/10.1139/v77-421
answered 19 hours ago
PoutnikPoutnik
74928
74928
add a comment |
add a comment |
Richeek is a new contributor. Be nice, and check out our Code of Conduct.
Richeek is a new contributor. Be nice, and check out our Code of Conduct.
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see: nrcresearchpress.com/doi/pdf/10.1139/v77-421
$endgroup$
– MaxW
19 hours ago